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尹万健教授课题组与合作者在Advanced Materials上发表论文

来源:中国竞彩网计算器 发布者:金霞发布时间:2017-05-16浏览次数:105

题 目:Bandgap Engineering of Stable Lead‐Free Oxide Double Perovskites for Photovoltaics

作 者:Qingde Suna,b, Jing Wanga,b, Wan-Jian Yina,b,* ,and Yanfa Yanc,*

单 位:

aSoochow Institute for Energy and Materials InnovationS (SIEMIS) College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, China

bJiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies, Soochow University, Suzhou 215006, China

cDepartment of Physics & Astronomy and Wright Center for Photovoltaics Innovation and Commercialization The University of Toledo Toledo, OH 43606, USA

摘要:Despite the rapid progress in solar power conversion efficiency of archetype organic–inorganic hybrid perovskite CH3NH3PbI3‐based solar cells, the long‐term stability and toxicity of Pb remain the main challenges for the industrial deployment, leading to more uncertainties for global commercialization. The poor stabilities of CH3NH3PbI3‐based solar cells may not only be attributed to the organic molecules but also the halides themself, most of which exhibit intrinsic instability under moisture and light. As an alternative, the possibility of oxide perovskites for photovoltaic applications is explored here. The class of lead‐free stable oxide double perovskites A2M(III)M(V)O6 (A = Ca, Sr, Ba; M(III) = Sb3+ or Bi3+; M(V) = V5+, Nb5+, or Ta5+) is comprehensively explored with regard to their stability and their electronic and optical properties. Apart from the strong stability, this class of double perovskites exhibits direct bandgaps ranging from 0.3 to 3.8 eV. With proper B site alloying, the bandgap can be tuned within the range of 1.0–1.6 eV with optical absorptions as strong as CH3NH3PbI3, making them suitable for efficient single‐junction thin‐film solar cell application.

影响因子21.95

原文链接:

https://onlinelibrary.wiley.com/doi/full/10.1002/adma.20170590110.1002/adma.201705901